The filename, directory name or volume label syntax is incorrect.

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Windows Central Question

I am unable to start any program from System32. Eg. Advance System Settings, Task Manger etc. I am getting the Error as - The filename, directory name or volume label syntax is incorrect.
 
If it happened recently, and something changed a path entry in the system32.ini file, perhaps rolling back to an earlier Restore Point would fix it by restoring the older (working) system32 ini file.