Okay, I've figured it out. It's been a while since I've attempted to transfer pictures directly from my PC to my phone using Zune. While I like Zune, boy oh boy, it can be extremely ******** at times.
So, in order for me to sync a single file to my phone using Zune, I can't just drag 'n drop like in iTunes or any other program, I have to use Zune (which doesn't show folders) to scan through the 4000 pictures I have in my picture library?!? Honestly... common sense?
Sod it, I've just uploaded it to Dropbox and I'll download it. The reason I wanted to use Zune was to prevent any possibility of decreased PQ.